🔬 Discovery

Condensation polymerization (Carothers)

Polimerización por condensación y química de poliésteres y poliamidas

Date
1929-1935 · confidence high
Place
DuPont Experimental Station, Wilmington, Delaware, United States
Credited to
Wallace Carothers
People
👤 Wallace Carothers1896–1937
Field
Matter & energy

What was discovered

Carothers experimentally confirms macromolecular theory by synthesising polyesters and polyamides of controlled molecular weight through stepwise condensation reactions, and formulates the equation relating conversion to chain length.

What it led to

  • Nylon (1935)
  • Neoprene
  • Polyesters (PET)
  • Quantitative polymer science
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Made possible

📄 Original publication

STUDIES ON POLYMERIZATION AND RING FORMATION. I. AN INTRODUCTION TO THE GENERAL THEORY OF CONDENSATION POLYMERSWallace H. Carothers · Journal of the American Chemical Society · 1929

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