📜 Theorem, law or theory

Coordination theory (Werner)

Teoría de la coordinación (complejos metálicos)

Date
1893 · confidence high
Place
University of Zurich, Switzerland
Credited to
Alfred Werner
People
👤 Alfred Werner1866–1919
Field
Matter & energy

What was discovered

Transition metals possess a secondary valence that fixes a number of ligands in defined geometries (octahedral, square planar); Werner demonstrated the optical isomerism of carbon-free complexes. He founds modern inorganic chemistry.

Nobel Prize in Chemistry 1913, the first inorganic chemist to be awarded it.

What it led to

  • Organometallic chemistry
  • Homogeneous catalysis
  • Bioinorganic chemistry (haemoglobin, chlorophyll)
  • Platinum drugs

Built on

  • Van't Hoff's stereochemistry
  • Blomstrand-Jorgensen salts

Made possible

  • cisplatin
  • transition-metal catalysts

📄 Original publication

Beitrag zur Konstitution anorganischer VerbindungenAlfred Werner · Zeitschrift für anorganische Chemie · 1893

Links