🛠️ Invention or technique

Freon-12 (dichlorodifluoromethane)

Freón-12 (diclorodifluorometano)

Date
1930 · confidence high
Place
General Motors Research Corporation, Dayton, Ohio, United States
Credited to
Thomas Midgley Jr., under Charles F. Kettering
Field
Matter & energy

What it is

Searching for a safe refrigerant to replace toxic or flammable gases such as ammonia or sulfur dioxide, Midgley synthesised dichlorodifluoromethane, colourless, odourless, non-toxic and non-flammable, marketed as Freon-12.

The team developed several related chlorofluorocarbons in the same years (R-11, R-22, R-113, R-114) through Kinetic Chemicals, a DuPont-General Motors joint venture.

What it led to

  • Widespread adoption of household refrigeration and air conditioning
  • Use as an aerosol propellant
  • CFC-driven catalytic ozone depletion (discovered 1974) and the Montreal Protocol ban
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Sources✓ verified 2026-09-28