🔬 Discovery

Photographic fixing with thiosulfate (Herschel)

Fijado fotográfico con tiosulfato (Herschel)

Date
1819-1839 · confidence high
Place
Slough, England, United Kingdom
Credited to
John Herschel
Field
Matter & energy

What was discovered

Herschel discovers in 1819 that sodium hyposulfite (thiosulfate) dissolves silver salts, and in 1839 suggests using it to fix photographic images. It made the daguerreotype and the calotype permanent.

Daguerre fixed with common salt and Talbot at first with salt and iodide; thiosulfate prevailed for its effectiveness.

What it led to

  • permanent photographic images
  • Herschel's terms photography, negative and positive
  • 19th-century processes that led to roll film
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Sources✓ verified 2026-11-06