🔬 Discovery

Spectral analysis and Kirchhoff's law of radiation

Análisis espectral y ley de la radiación de Kirchhoff

Date
1859 · confidence high
Place
Heidelberg, Germany
Credited to
Gustav Kirchhoff; Robert Bunsen
People
👤 Gustav Kirchhoff1824–1887👤 Robert Bunsen1811–1899
Field
Communication

What was discovered

Every element emits and absorbs light in characteristic lines, which explains the Fraunhofer lines as absorption in the solar atmosphere; Kirchhoff states that emission and absorption are proportional and poses the black-body problem. Spectroscopy becomes a universal tool.

In 1860 Kirchhoff posed the black body as a theoretical problem that Planck would solve in 1900.

What it led to

  • Discovery of elements (caesium, rubidium, helium)
  • Astrophysics
  • Black-body problem and quantum theory
  • Spectral series (Balmer) and the Bohr model
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Made possible

📄 Original publication

Chemische Analyse durch SpectralbeobachtungenG. Kirchhoff, R. Bunsen · Annalen der Physik · 1860

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